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41.
The characteristics of groundwater systems and groundwater contamination in Finland, Norway and Iceland are presented, as they relate to outbreaks of disease. Disparities among the Nordic countries in the approach to providing safe drinking water from groundwater are discussed, and recommendations are given for the future. Groundwater recharge is typically high in autumn or winter months or after snowmelt in the coldest regions. Most inland aquifers are unconfined and therefore vulnerable to pollution, but they are often without much anthropogenic influence and the water quality is good. In coastal zones, previously emplaced marine sediments may confine and protect aquifers to some extent. However, the water quality in these aquifers is highly variable, as the coastal regions are also most influenced by agriculture, sea-water intrusion and urban settlements resulting in challenging conditions for water abstraction and supply. Groundwater is typically extracted from Quaternary deposits for small and medium municipalities, from bedrock for single households, and from surface water for the largest cities, except for Iceland, which relies almost entirely on groundwater for public supply. Managed aquifer recharge, with or without prior water treatment, is widely used in Finland to extend present groundwater resources. Especially at small utilities, groundwater is often supplied without treatment. Despite generally good water quality, microbial contamination has occurred, principally by norovirus and Campylobacter, with larger outbreaks resulting from sewage contamination, cross-connections into drinking water supplies, heavy rainfall events, and ingress of polluted surface water to groundwater.  相似文献   
42.
Landslides are a major category of natural disasters, causing loss of lives, livelihoods and property. The critical roles played by triggering (such as extreme rainfall and earthquakes), and intrinsic factors (such as slope steepness, soil properties and lithology) have previously successfully been recognized and quantified using a variety of qualitative, quantitative and hybrid methods in a wide range of study sites. However, available data typically do not allow to investigate the effect that earlier landslides have on intrinsic factors and hence on follow-up landslides. Therefore, existing methods cannot account for the potentially complex susceptibility changes caused by landslide events. In this study, we used a substantially different alternative approach to shed light on the potential effect of earlier landslides using a multi-temporal dataset of landslide occurrence containing 17 time slices. Spatial overlap and the time interval between landslides play key roles in our work. We quantified the degree to which landslides preferentially occur in locations where landslides occurred previously, how long such an effect is noticeable, and how landslides are spatially associated over time. We also investigated whether overlap with previous landslides causes differences in landslide geometric properties. We found that overlap among landslides demonstrates a clear legacy effect (path dependency) that has influence on the landslide affected area. Landslides appear to cause greater susceptibility for follow-up landslides over a period of about 10  years. Follow-up landslides are on average larger and rounder than landslides that do not follow earlier slides. The effect of earlier landslides on follow-up landslides has implications for understanding of the landslides evolution and the assessment of landslide susceptibility.  相似文献   
43.
The prediction of soil moisture content, θ, as a function of depth, z, and time, t, is of fundamental importance for applications in many hydrological processes. The main objective of this paper is to provide an approach to solve this problem at a local scale in soils with vegetation. The matching of soil moisture vertical profiles observed under natural conditions in grassy plots and their simulations by a conceptual model is presented. Experimental measurements were performed in a plot located in Central Italy, complete with hydrometeorological sensors specifically set up and equipped with a time domain reflectometry system providing the water content, θe(z, t). A conceptual model framework earlier proposed for two‐layered soil vertical profiles was modified and adopted for simulations. The changes concern the incorporation of evapotranspiration, the reduction of the original model for applications also to homogeneous soil vertical profiles, and a correction for the differences existing between assumed and observed initial moisture contents. In the model calibration, it was found that the effects of vegetation could be represented adequately by a fictitious soil vertical profile with a more permeable upper layer of saturated hydraulic conductivity, Ks, independent of time. Then, for the validation events, the model simulations in the stages of both infiltration and redistribution/evapotranspiration reproduced appropriately θe(z, t) with typical values of root mean square error in the range 0.0017–0.0657. Similar results were obtained by applying the modified two‐layered model for simulations of experimental data observed in three other plots located in Northern Italy and Germany. For all four vegetated sites, the two‐layer profile better matched the experimental data than the assumption of a homogeneous profile. Thus, the conceptual approach based on a two‐layered scheme for representing θ(z, t) in soils with vegetation appears to be appropriate for many hydrological applications. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   
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In the past two decades, optical properties of chromophoric dissolved organic matter (CDOM) in marine environments have been extensively studied. Many of these studies report CDOM properties for the offshore environment where this complex mixture of optically active compounds is strongly diluted. Nevertheless, autochthonous and allochthonous sources have been identified and sinks related to photodegradation and bacterial activity have been demonstrated. The calculation of the spectral slope of the CDOM absorption curve has been proven to be useful and is often reported. However, a rigorous uncertainty analysis of the slope calculation is rarely reported. In this paper, we propose a method to evaluate the uncertainty of CDOM spectral slope calculated between 270 and 400 nm, using both naturally sampled and artificial solutions. We use these results to study the ultra-oligotrophic waters of the Mediterranean Sea (central eastern basin), where little is known about CDOM spatial distribution. We show that dilutions of both artificial and natural samples produce a Gaussian distribution of spectral slopes, indicating that consistent values may be determined, with a typical uncertainty of ±0.0004 nm−1 when absorption at 300 nm was greater then 0.1 m−1 (0.1 m pathlength). Comparing the distribution of spectral slopes from central eastern basin samples to a Gaussian distribution, we show differences between measurements that were significantly different. These values allow us to distinguish possible sources (algal derived CDOM), sinks (e.g. photo-bleaching) at different depths. We propose a subdivision of CDOM compounds into refractory and semilabile/refractory pools and evaluate the CDOM spectral slope of algal derived CDOM released at or near deep chlorophyll maximum.  相似文献   
48.
An indigenous bacterial strain of Delftia sp. capable of degrading 2,4‐dicholorophenol and an indigenous bacterial community that degrades 2,4,6‐trichlorophenol (TCP) were employed to inoculate continuous down‐flow fixed‐bed reactors. Continuous‐reactors were constructed from PVC employing hollow PVC cylinders as support material. Synthetic wastewater was prepared by dissolving the corresponding chlorophenol in non‐sterile groundwater. Biodegradation was evaluated by spectrophotometry, chloride release, GC, and microbial growth. Detoxification was evaluated by using Daphnia magna as test organism. Delftia sp. was able to remove an average of 95.6% of DCP. Efficiency in terms of chemical oxygen demand (COD) was of 88.9%. The indigenous bacterial community that degrades TCP reached an average efficiency of 96.5 and 91.6% in terms of compound and COD removal, respectively. In both cases stoichiometric removal of chloride and detoxification was achieved. When synthetic wastewater feed was cut off for 7 days, both reactors showed a fast recovery after inflow restarting, reaching average outlet concentration values within 36 h. The promising behavior of the microorganisms and the low cost of the reactors tested allow us to suggest their possible application to remediation processes.  相似文献   
49.
The impact of diffuse pollution, agricultural land use and climate change on the long-term response of subsurface–surface water quality is not well understood, but is a prerequisite for evaluation of water management options. The goal of this study is to model geochemical evolution of water chemistry from the infiltration through soil into the unsaturated zone, transport through bedrocks and granular aquifers to a river in order to identify zones of steep concentration gradients and high dynamics under transient flow conditions. A numerical model was constructed comprising a 2-D 1,500 m × 150 m vertical cross-section of typical sedimentary rock formations, a glacio-fluvial quaternary gravel aquifer in the valley and soil layers. The model coupled saturated/un-saturated flow and reactive transport under steady state and transient conditions. Geochemical interactions, include intra-aqueous kinetic reactions of oxygen with dissolved organic matter, as well as kinetics of carbonate dissolution/precipitation. This model section was chosen to provide insight in to the principal processes and time scales affecting water chemistry along different flow paths. The numerical simulator MIN3P was used, a finite volume program for variably saturated subsurface flow and multi-component reactive transport. The results show that subsurface water residence times range from approximately 2 to 2,000 years. Different zones are to be expected with respect to the development of mineral equilibria; namely, purely atmospherically influenced, as well as open and closed system carbonate dissolution. Short-term responses to daily averaged changes in precipitation, however, are only visible to some extent in the shallower and near-river parts of flow system and solute loads. This can most likely be explained by directional changes in flow paths, indicating that equilibrium geochemical condition predominate at the hillslope scale, i.e. water quality depends on transport pathways rather than on kinetic effects. The extent of reducing conditions is controlled by the presence of organic-rich layers (i.e. peat deposits), the dissolution kinetics of aquifer organic matter and the subsequent mixing with oxygenated water by hydrodynamic dispersion.  相似文献   
50.
The Orbetello lagoon, one of the largest Western Mediterranean lagoons, was affected by high algal blooms and severe anoxic crises in 1992 and 1993, with fish mortality throughout most of the lagoon and a drastic reduction of benthic species. Many measures were undertaken between 1994 and 1996 to remove the severe eutrophication of this lagoon. Such measures included harvesting of the floating seaweed biomass, removal of all wastewater and sea channel enlargement by dredging activity. The aim of the present research was to study the macrozoobenthic assemblage in 1999 and to compare it with previous research in order to assess the recovery of the lagoon. A total of 106 taxa and 45,175 individuals were collected in three areas (sea inlets, western and eastern lagoon) having different organic matter loading during winter and summer. The results of multivariate and correlation analyses indicated that trophic status and its seasonal dynamics were crucial in determining species distribution among the different areas. Moreover, comparison of the macrozoobenthic structure between winter 1995 and 1999 showed differences in species composition and structural parameters in the western and eastern lagoon, where a clear recovery of benthic assemblages was observed in 1999. However, the dominance of opportunistic species in most of the lagoon and the decrease in some structural parameters during summer suggested that this basin still presented signs of disturbance in 1999, six years after the last extended anoxic crises and even after completion of the restoration measures carried out in the environment. It was hypothesized that a secondary disturbance, sustained by a high seasonal release of nutrients from the sediments, could create considerable deviations from the expected improvement in benthic conditions.  相似文献   
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